New Polymer Coating Heals Itself With 1 Minute of UV Exposure

By Patrick Morgan | April 21, 2011 9:16 am

What’s the News: Researchers have developed the fastest yet self-healing polymer: The new class of materials dubbed “metallo-supramolecular polymers” heal after only one minute under UV light even when they’re repeatedly cut. This could eventually lead to self-repairing floor varnishes, automotive paints, and other applications. University of Illinois at Urbana researchers Nancy Sottos and Jeffrey Moore say these these healable polymers “offer an alternative to the damage-and-discard cycle” that is rampant in our consumer society, and could pave the way for products “that have much greater lifespans than currently available materials.” (You can see the process below in a press video from Case-Western Reserve University.)

How the Heck:

  • Unlike most polymers, which are composed of long molecular chains, metallo-supramolecular polymers are made of “short chains that are glued together with metal ions.”
  • Scratches break up the polymer chains of metallo-supramolecular polymers. By shining intense UV light on and near the scratch, the metal ions heat to over 220°C in 30 seconds, depolymerizing the material.
  • While still depolymerized, the unglued particles act like a liquid and flow together again, smoothing out scratches in the process.
  • And when the intense UV light is removed, the metal quickly cools, and the now-smooth surface solidifies in seconds.
  • The polymer is made up from many bonded molecules of a complicated macromonomer custom designed to separate under the proper conditions.

What’s the Context:

Not So Fast: Don’t expect to purchase a self-healing car anytime soon. “What we have reported is not something that I expect to be commercialized tomorrow or next year,” Weder told MSNBC. “It’s really a first generation of a class of materials that need further refinement.”

The Future Holds: The present study healed cars using only intense ultraviolet light; now they’re looking into whether other light wavelengths are more effective.

Reference: Mark Burnworth, Liming Tang, Justin R. Kumpfer, Andrew J. Duncan, Frederick L. Beyer, Gina L. Fiore, Stuart J. Rowan & Christoph Weder. “Optically healable supramolecular polymers.” Nature. doi:10.1038/nature09963

  • Georg

    That sounds interesting,
    but stirring water with a magnet stirrer and adding some
    dry ice, is that unavoidable ?

  • Brian Too

    This is awfully cool. What’s impressive is they have a material that reassembles the polymers when heated. One can imagine the atoms simply disassociating into a disorganized mess, moreso even than when scratched, when the heating occurs.

  • Concerned

    T-1000, anyone?

    Seriously, very cool advancement here. Can’t wait to see the real world applications (far off, I know, but one can imagine!)

  • Lola

    Are there any health consequences? What are the byproducts? Can workers work with these polymers safely?

  • bearing

    One who is not willing to learn is not worth teaching

  • Zobacz

    I would like to get across my gratitude for your kind-heartedness giving support to those people who should have assistance with this one matter. Your real commitment to getting the solution across appeared to be wonderfully interesting and have continually empowered women like me to realize their ambitions. The warm and helpful information signifies a lot a person like me and even further to my colleagues. Thanks a lot; from each one of us.

  • Random

    Does this mean my car would melt if I left it out in the sun for too long? I understand that the UV light has to be intense to melt the polymer down, but, given enough time, would this stuff slowly deform under lower levels?


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