Nuclear Technology Abandoned Decades Ago Might Give Us Safer, Smaller Reactors

By M. Mitchell Waldrop | February 26, 2019 4:38 pm
nuclear power plant

(Credit: Daniel Prudek/Shutterstock)

Troels Schönfeldt can trace his path to becoming a nuclear energy entrepreneur back to 2009, when he and other young physicists at the Niels Bohr Institute in Copenhagen started getting together for an occasional “beer and nuclear” meetup.

The beer was an India pale ale that they brewed themselves in an old, junk-filled lab space in the institute’s basement. The “nuclear” part was usually a bull session about their options for fighting two of humanity’s biggest problems: global poverty and climate change. “If you want poor countries to become richer,” says Schönfeldt, “you need a cheap and abundant power source.” But if you want to avoid spewing out enough extra carbon dioxide to fry the planet, you need to provide that power without using coal and gas.

It seemed clear to Schönfeldt and the others that the standard alternatives simply wouldn’t be sufficient. Wind and solar power by themselves couldn’t offer nearly enough energy, not with billions of poor people trying to join the global middle class. Yet conventional nuclear reactors — which could meet the need, in principle — were massively expensive, potentially dangerous and anathema to much of the public. And if anyone needed a reminder of why, the catastrophic meltdown at Japan’s Fukushima Daiichi plant came along to provide it in March 2011.

On the other hand, says Schönfeldt, the worldwide nuclear engineering community was beginning to get fired up about unconventional reactor designs — technologies that had been sidelined 40 or 50 years before, but that might have a lot fewer problems than existing reactors. And the beer-and-nuclear group found that one such design, the molten salt reactor, had a simplicity, elegance and, well, weirdness that especially appealed.

The weird bit was that word “molten,” says Schönfeldt: Every other reactor design in history had used fuel that’s solid, not liquid. This thing was basically a pot of hot nuclear soup. The recipe called for taking a mix of salts — compounds whose molecules are held together electrostatically, the way sodium and chloride ions are in table salt — and heating them up until they melted. This gave you a clear, hot liquid that was about the consistency of water. Then you stirred in a salt such as uranium tetrafluoride, which produced a lovely green tint, and let the uranium undergo nuclear fission right there in the melt — a reaction that would not only keep the salts nice and hot, but could power a city or two besides.

molten salt vials

A compound combining various salts (including uranium tetrafluoride), shown as a solid at left and a liquid at right, is one example of a compound that could be used in a molten salt reactor. (Credit: ORNL/US DOE)

Weird or not, molten salt technology was viable; the Oak Ridge National Laboratory in Tennessee had successfully operated a demonstration reactor back in the 1960s. And more to the point, the beer-and-nuclear group realized, the liquid nature of the fuel meant that they could potentially build molten salt reactors that were cheap enough for poor countries to buy; compact enough to deliver on a flatbed truck; green enough to burn our existing stockpiles of nuclear waste instead of generating more — and safe enough to put in cities and factories. That’s because Fukushima-style meltdowns would be physically impossible in a mix that’s molten already. Better still, these reactors would be proliferation resistant, because their hot, liquid contents would be very hard for rogue states or terrorists to hijack for making nuclear weapons.

Molten salt reactors might just turn nuclear power into the greenest energy source on the planet.

Crazy? “We had to try,” says Schönfeldt. So in 2014 he and his colleagues launched Seaborg Technologies, a Copenhagen-based start-up named in honor of the late Glenn Seaborg, a Manhattan Project veteran who helped pioneer the peaceful uses of nuclear energy. With Schönfeldt as chief executive officer, they set about turning their vision into an ultracompact molten salt reactor that could serve the developed and developing world alike.

They weren’t alone: Efforts to revive older nuclear designs had been bubbling up elsewhere, and dozens of start-ups were trying to commercialize them. At least half a dozen of these start-ups were focused on molten salt reactors specifically, since they were arguably the cleanest and safest of the lot. Research funding agencies around the world had begun to pour millions of dollars per year into developing molten salt technology. Even power companies were starting to make investments. A prime example was the Southern Company, a utility conglomerate headquartered in Atlanta, Georgia. In 2016, the company started an ambitious molten salt development program in collaboration with Oak Ridge and TerraPower, a nuclear research company in Bellevue, Washington.

“In the next 20 to 30 years, the energy environment is going to undergo a major transformation to a low- to no-carbon future,” says Nick Irvin, Southern’s director of research and development. There will be far fewer centralized power plants and many more distributed sources like wind and solar, he says. Molten salt reactors fit ideally into this future, he adds, because of both their inherent safety and their ability to consume spent nuclear fuel from traditional nuclear reactors.

molten salt reactor

A molten salt reactor differs from a conventional nuclear reactor in a number of ways, starting with the fact that it uses nuclear fuel that’s liquid instead of solid. This has profound implications for safety. For example, meltdowns would be a non-issue: The fuel is already molten. And if temperatures in the fuel mix get too high for any reason, a plug of frozen salt below the reactor will melt and allow everything to drain into an underground holding tank for safekeeping. Long-lived nuclear waste would also be a non-issue: A chemical system would continuously extract reaction-slowing fission products from the molten fuel, which would allow plutonium and all the other long-half-life fissile isotopes to be completely consumed.

Getting there won’t be easy — not least because hot molten salts can be just as corrosive as they sound. Every component that comes into contact with the brew will have to be made of a specialized, high-tech alloy that can resist them. “You dissolve the uranium in the salt,” says Nathan Myhrvold, a venture capitalist who serves as vice chairman of TerraPower’s board. “What you have to make sure is that you don’t dissolve your reactor in it!”

Certainly no one expects to have a prototype power plant operating before the mid-2020s, or to field full-scale commercial reactors until the 2030s. Still, says Schönfeldt, “it will be exceedingly hard, but that is significantly better than impossible.”

Rethinking Nuclear

To Rachel Slaybaugh, today’s surge of entrepreneurial focus on nuclear technology is astonishing. “It feels like we’re at the beginning of a movement, with an explosion of ideas,” says Slaybaugh, a nuclear engineer at the University of California, Berkeley, who has written about green energy options in the Annual Review of Environment and Resources.

But, as nuclear engineer Leslie Dewan points out, this explosion is also something of a throwback to the post–World War II era. “Nuclear power technology was incredibly new,” says Dewan, who in 2011 cofounded one of the first of the molten salt start-ups, Transatomic Power in Cambridge, Massachusetts. It was a time of blue-sky thinking, she says, “where they were trying many, many different types of technologies, running experiments, building and prototyping.”

atom

Atoms may be the smallest unit of matter, but they are made up of even smaller subunits, including protons, neutrons and electrons. The energy that binds the protons and neutrons together in the atom’s nucleus is enormous, and can be released and put to use during a nuclear reaction.

The basics had been known since 1938, when German scientists discovered that firing a neutron into certain heavy atomic nuclei would cause the nucleus to fission, or split into two pieces. The rupture of such a “fissile” nucleus would release an enormous amount of energy, plus at least two new neutrons. These neutrons could then slam into nearby nuclei and trigger the release of more energy, plus 4 neutrons — then 8, 16, 32 and so on in an exponentially growing chain reaction.

This runaway energy release could produce a very powerful bomb, as the wartime Manhattan Project demonstrated. But taming it, and turning the chain reaction into a safe, steady-state heat source for power production, was a lot trickier.

nuclear fission

Fission is at the heart of nuclear energy production. Fission happens when a free neutron slams into an unstable atomic nucleus and shatters it into two or more “fission products”: lighter elements such as krypton and barium that cluster around the middle of the periodic table. Thanks to Einstein’s famous equation E = mc2, this process also transforms a tiny bit of the original nucleus’s mass into an immense amount of energy.

That’s where all the postwar experimentation came in. There were reactors fueled by uranium, which comes out of the ground containing virtually the only fissile isotope found in nature, uranium-235. There were reactors known as breeders, which could accomplish the magical-sounding feat of producing more fuel than they consumed. (Actually, they relied on the fact that uranium is “fertile,” meaning that its most abundant isotope, uranium-238, almost never undergoes fission by itself — but it can absorb a neutron and turn into highly fissile plutonium-239.) And there were reactors fueled with thorium, a fertile element that sits two slots to the left of uranium in the periodic table, and is about three times more abundant in the Earth’s crust. A neutron will turn its dominant isotope, thorium-232, into fissile uranium-233.

An element, such as carbon or uranium, is defined by the number of protons in its nucleus: Carbon has 6, uranium 92. But atoms may vary in the number of neutrons, producing slightly different flavors, or isotopes, of an element. For example, the most common form of carbon is carbon-12, which has 6 protons and 6 neutrons, and is stable. But other isotopes include carbon-13, which is also stable, and carbon-14, which is unstable and radioactive. Uranium’s most common form is uranium-238, which has 92 protons and 146 neutrons, and decays only after billions of years. Other, less stable isotopes include uranium-235 (92 protons and 143 neutrons) and uranium-233 (92 protons and 141 neutrons), both of which can undergo nuclear fission if they are struck by a neutron.

An element, such as carbon or uranium, is defined by the number of protons in its nucleus: Carbon has 6, uranium 92. But atoms may vary in the number of neutrons, producing slightly different flavors, or isotopes, of an element. For example, the most common form of carbon is carbon-12, which has 6 protons and 6 neutrons, and is stable. But other isotopes include carbon-13, which is also stable, and carbon-14, which is unstable and radioactive. Uranium’s most common form is uranium-238, which has 92 protons and 146 neutrons, and decays only after billions of years. Other, less stable isotopes include uranium-235 (92 protons and 143 neutrons) and uranium-233 (92 protons and 141 neutrons), both of which can undergo nuclear fission if they are struck by a neutron.

At the same time, designers were trying out different types of coolant: the fluid that circulates through the reactor core, absorbs the heat being produced by the fission reactions, and carries it out to where the heat can do something useful like running a standard steam turbine to generate electricity. Some opted for ordinary water: an abundant, familiar substance that carries a lot of heat per unit of volume. But others went with high-temperature substances such as liquid sodium metal, helium gas or even molten lead. “Coolants” like these could keep a reactor running at 700 degrees Celsius or more, which would make it substantially more efficient at generating power.

By the 1960s, researchers had tested reactors featuring combinations of all these options and more. But the approach that won out for commercial power production — and that is still used in virtually all of the 454 nuclear plants operating around the world — was the water-cooled uranium reactor. This wasn’t necessarily the best nuclear design, but it was one of the first: Water-cooled reactors were originally developed in the 1940s to power submarines. So in the 1950s, when the Eisenhower administration launched a high-profile push to harness nuclear energy for peaceful purposes, the technology was adapted for civilian use and scaled up enormously. Other designs were left for later, if ever. By the 1960s and 1970s, second-generation water-cooled reactors were being deployed globally.

Even then, however, there were many in the field who were uneasy with that choice. Among the most notable was nuclear physicist Alvin Weinberg, a Manhattan Project veteran and director of the Oak Ridge National Laboratory. Weinberg had participated in the development of water-cooled reactors, and knew that they had some key vulnerabilities — including water’s low boiling point, just 100°C at normal atmospheric pressure.

Commercial nuclear plants could get that up to 325°C or so by pressurizing the reactor vessel. But as Weinberg and others knew very well, that was not enough to rule out the nightmare of nightmares: a meltdown. All it would take was some freak accident that interrupted the flow of water through the core and trapped all the heat inside. You could shut down power production by dropping rods of boron or cadmium into the reactor core to soak up neutrons and stop the chain reaction. But nothing could stop the heat produced by the decay of fission products — the melange of short-lived but fiercely radioactive elements that inevitably build up inside an active reactor as nuclei split in two.

nuclear chain reaction

When the nuclei of certain “fissile” isotopes such as uranium-235 are struck by a neutron, they don’t just split apart. They also release at least two additional neutrons, which can then go on to split two more nuclei. This produces at least 4 additional neutrons – then 8, 16, 32, 64 and so on. The result is an exponentially growing chain reaction, which can produce a nuclear explosion if it’s allowed to run away — or useful nuclear power if it’s contained and controlled inside a reactor.

Unless the operators managed to restore the coolant flow within a few hours, that trapped fission-product heat would send temperatures soaring past the 325°C mark, turn the water into high-pressure steam, and reduce the solid fuel to a radioactive puddle melting its way through the reactor vessel floor. Soon after, the vessel would likely rupture and send a pressurized plume of fission products into the atmosphere. Included would be radioactive strontium-90, iodine-131 and caesium-137 — extremely dangerous isotopes that can easily enter the food chain and end up in the body.

To forestall such a catastrophe, designers had equipped the commercial water-cooled reactors with all manner of redundancies and emergency backup cooling systems. But to Weinberg’s mind, that was a bit like installing fire alarms and sprinkler systems in a house built of papier-mâché. What you really wanted was the nuclear equivalent of a house built of fireproof brick — a reactor that based its safety on the laws of physics, with no need for operators or backup systems to do anything.

Weinberg and his team at Oak Ridge believed that they could come very close to that ideal with the molten salt reactor, which they had been working on since 1954. Such a reactor couldn’t possibly suffer a meltdown, even in an accident: The molten salt core was liquid already. The fission-product heat would simply cause the salt mix to expand and move the fuel nuclei farther apart, which would dampen the chain reaction.

Pressure would be a non-issue as well: The salts would have a boiling point far higher than any temperature the fission products could produce. (One common choice for nuclear applications is FLiBe, a mix of lithium fluorides and beryllium fluorides that doesn’t boil until 1,400°C, about the temperature of a butane blowtorch.) So the reactor vessel would never be in danger of rupture from molten salt “steam.” In fact, the reactor would barely shift from its normal operating pressure of one atmosphere.

Better still, the molten core would trap fission products far more securely than in solid-fueled reactors. Caesium, iodine and all the rest would chemically bind with the salts the instant they were created. And since the salts could not boil away in even the worst accident, these fission products would be held in place instead of being free to drift off and take up radioactive residence in people’s bones and thyroid glands.

And just in case, the liquid nature of the fuel allowed for a simple fail-safe known as a freeze plug. This involved connecting the bottom of the reactor vessel to a drain pipe, which would be plugged with a lump of solid fuel salt kept frozen by a jet of cool gas. If the power failed and the gas flow stopped, or if the reactor got too hot, the plug would melt and gravity would drain the contents into an underground holding tank. The mix would then cool, solidify and remain in the tank until the crisis was over — salts, fuel, fission products and all.

Molten Salt Success, Then a Detour

Weinberg and his team successfully demonstrated all this in the Molten Salt Reactor Experiment, an 8-megawatt prototype that ran at Oak Ridge from 1965 to 1969. The corrosiveness of the salts was a potential threat to the long-term integrity of pipes, pumps and other parts, but the researchers had identified a number of corrosion-resistant materials they thought might solve the problem. By the early 1970s, the group was well into development of an even more ambitious prototype that would allow them to test those materials as well as to demonstrate the use of thorium fuel salts instead of uranium.

fertile isotopes

practical source of fission energy. Uranium-235, which comprises 0.7 percent of natural uranium ore, can sustain a chain reaction all by itself; it is the primary energy source for nuclear power reactors operating in the world today. Uranium-238, which comprises virtually all the other atoms in mined uranium, is “fertile”: it can’t sustain a chain reaction by itself, but when it’s hit by a neutron it can transform into the highly fissile isotope plutonium-239. Likewise with thorium-232: Slamming it with a neutron can turn it into the fissile isotope uranium-233.

The Oak Ridge physicists were also eager to try out a new system for dealing with the waste fission products — one that again took advantage of the fuel’s liquid nature, but had been tested only in the laboratory. The idea was to siphon off a little of the reactor’s fuel mix each day and run it through a nearby purification system, which would chemically extract the fission products in much the same way that the kidneys remove toxins from the bloodstream. The cleaned-up fuel would then be circulated back into the reactor, which could continue running at full power the whole time. This process would not only keep the fission products from building up until they snuffed out the chain reaction — a problem for any reactor, since these elements tend to absorb a lot of neutrons — but it would also enhance the safety of molten salt still further. Not even the worst accident can contaminate the countryside with fission products that aren’t there.

But none of it was to be. Officials in the US nuclear program terminated the Oak Ridge molten salt program in January 1973 — and fired Weinberg.

The nuclear engineering community was just too heavily committed to solid fuels, both financially and intellectually. Practitioners already had decades of experience with experimental and commercial solid-fueled reactors, versus that one molten salt experiment at Oak Ridge. A huge infrastructure existed for processing and producing solid fuel. And, not incidentally, the US research program was committed to a grand vision for the global nuclear future that would expand this infrastructure enormously — and that, viewed with 20-20 hindsight, would lead the nuclear industry into a trap.

Key to that vision was a different way of dealing with the buildup of fission products. Since Oak Ridge–style continuous purification wasn’t an option in a solid-fuel reactor, water-cooled or otherwise, standard procedure called for burning fuel until the fission products rendered it useless, or spent. In water-cooled power reactors this took roughly three years, at which point the spent fuel would be switched out for fresh, then stored at the bottom of a pool of water for a few years while the worst of its fission-product radioactivity decayed.

radioactive half-life

Radioactivity forms when an unstable atomic nucleus sheds its excess energy by firing off a high-speed particle. This allows the nucleus to “decay,” or settle into a more stable form. The type of particle that’s emitted depends on the isotope involved, but primarily is alpha, beta or gamma. The rate of decay depends on the isotope’s half-life: the time it takes for half the original sample of nuclei to decay.

From there, the plan was to recycle it. Counting the remaining uranium, plus the plutonium that had formed from neutrons hitting uranium-238 nuclei, the fuel still contained most of the potential fission energy it had started with. So there was to be a new, global network of reprocessing plants that would chemically extract the fission products for disposal, and turn the uranium and plutonium into fresh fuel. That network, in turn, would ultimately support a new generation of sodium-cooled breeder reactors that would produce plutonium by the ton — thus solving what was then thought to be an acute shortage of the uranium needed to power the all-nuclear global economy of the future.

But that plan started to look considerably less visionary in May 1974, when India tested a nuclear bomb made with plutonium extracted from the spent fuel of a conventional reactor. Governments around the world suddenly realized that global reprocessing would be an invitation to rampant nuclear weapons proliferation: In plants handling large quantities of pure plutonium, it would be entirely too easy for bad actors to secretly divert a few kilograms at a time for bombs. So in April 1977, US President Jimmy Carter banned commercial reprocessing in the United States, and much of the rest of the world followed.

closed nuclear fuel cycle

The vision for nuclear energy 50 years ago included a “closed loop” for nuclear fuels. In this scenario, most fuels would be reprocessed and cycled back into reactors to make more energy. The only wastes would be fission products, which are radioactive for a few hundred years at most.

That helped cement the already declining interest in breeder reactors, which made no sense without reprocessing plants to extract the new-made plutonium, and left the world with a nasty disposal problem. Instead of storing spent fuel underwater for a few years, engineers were now supposed to isolate it for something like 240,000 years, thanks to the 24,100-year half-life of plutonium-239. (The rule of thumb for safety is to wait 10 half-lives, which reduces radiation levels more than a thousand-fold.) No one has yet figured out how to guarantee isolation for that span of time. Today, there are nearly 300,000 tons of spent nuclear fuel still piling up at reactors around the world, part of an as yet unresolved long-term storage problem.

In retrospect, those 1970s-era nuclear planners would have done well to put serious money back into Oak Ridge’s molten salt program: As developers there tried to point out at the time, the continuous purification approach could have solved both the spent-fuel and proliferation problems at a stroke.

The proliferation risk would be minimal because — unlike the kind of reprocessing plants envisioned for the breeder program — the Oak Ridge system would never isolate uranium-235, plutonium-239 or any other fissile material. Instead, these isotopes would stay in the cleaned-up fuel salts at concentrations far too low to make a bomb. They would be circulated back into the reactor, where they could continue fissioning until they were completely consumed.

The reactor’s purification system would likewise offer a solution to the spent fuel issue. It would strip out the reaction-quenching fission products from the fuel almost as quickly as they formed, which would potentially allow the reactor to run for decades at a stretch with only an occasional injection of fresh fuel to replace what it burned. Some of that fuel could even come from today’s 300,000-ton backlog of spent solid fuel.

Admittedly, it would take centuries for even a large network of molten salt reactors to work through the full backlog. But burning it would eliminate the need to safely store it for thousands of centuries. By consuming the long-lived isotopes like plutonium-239, molten salt reactors could reduce the nuclear waste stream to a comparatively small volume of fission products having half-lives of 30 years or less. By the 10 half-life rule, this waste would then need to be isolated for just 300 years. That’s not trivial, says Schönfeldt, “but it’s something that can be handled” — say, by encasing the waste in concrete and steel, or putting it down a deep borehole.

Unfortunately, the late 1970s was not a good time for reviving any kind of nuclear program, molten salt or otherwise. Public mistrust of nuclear energy was escalating rapidly, thanks to rising concerns over safety, waste and weapons proliferation. The power companies’ patience was wearing thin, thanks to the skyrocketing, multibillion-dollar cost of standard water-cooled reactors. And then in March 1979 came a partial meltdown at Three Mile Island, a conventional nuclear plant near Harrisburg, Pennsylvania. In April 1986, another catastrophe hit with the fire and meltdown at the Chernobyl plant in Ukraine.

The resulting backlash against nuclear power was so strong that new plant construction effectively ceased — which is why most of the nuclear reactors operating today are at least three to four decades old. And nuclear power research stagnated, as well, with most of the money and effort going into ensuring the safety of those aging plants.

“The nuclear industry was not in an innovation frame of mind for 30 years,” says TerraPower’s Myhrvold.

open nuclear fuel cycle

In the 1970s, the threat that reprocessed fuels could be secretly diverted to make nuclear weapons led the United States and many other nations to reject the closed fuel cycle. Instead, they have opted to dispose of spent nuclear fuel after just one pass through the reactor. But because the fuel now contains long-half-life isotopes like plutonium-239, the wastes must be managed and stored for more than 200,000 years before they will be considered safe. No one knows how to guarantee that spent fuel will remain undisturbed for that span of time — one of the many safety concerns that have dogged nuclear energy programs.

Old Tech Revival

This defensive crouch lasted well into the new century, while the molten salt concept fell further and further into obscurity. That began to change only in 2000, when Kirk Sorensen came across a book describing what the molten salt program had accomplished at Oak Ridge.

“Why didn’t we do it this way in the first place?” he remembers wondering.

Sorensen, then a NASA engineer in Huntsville, Alabama, was so intrigued that he tracked down the old Oak Ridge technical reports, which were moldering in file cabinets, and talked NASA into paying to have them scanned. The files filled up five compact discs, which he copied and sent around to leaders in the US energy industry. “I received no response,” he says. So in 2006, in hopes of reaching somebody who would find the concept as compelling as he did, he uploaded the documents to energyfromthorium.com, a website he’d created with his own money.

That strategy worked — slowly. “I would give Kirk Sorensen personal credit,” says Lou Qualls, a nuclear engineer at Oak Ridge who became the Department of Energy’s first national technical director for molten salt reactors in 2017. “So Kirk is one of those voices out in the wilderness, and for a long time people would go, ‘We don’t even know what you’re talking about.’” But once the old reports became available online, “people started to look at the technology, to understand it, see that it had a history,” Qualls says. “It started getting more credibility.”

It helped that rising concerns about climate change — and the ever-growing backlog of spent nuclear fuel — had put many nuclear engineers in the mood for a radical rethink of their field. They could see that incremental improvements in standard reactor technology weren’t getting anywhere. Manufacturers had been hyping their “Generation III” designs for water-cooled reactors with enhanced safety features, but these were proving to be just as slow and expensive to build as their second-generation predecessors from the 1970s.

So instead, there was a move to revive the old reactor concepts and update them into a whole new series of Generation IV reactors: devices that would be considerably smaller and cheaper than their 1,000-megawatt, multibillion-dollar predecessors, with safety and proliferation resistance built in from the start. Among the most prominent symbols of this movement was TerraPower. Launched in 2008 with major funding from Microsoft cofounder Bill Gates, the company immediately started development of a liquid sodium-cooled device called the Traveling Wave Reactor.

The molten salt idea was definitely on the Gen IV list. Schönfeldt remembers getting excited about it as early as 2008. At MIT, Dewan and her fellow graduate student Mark Massie first encountered the idea in 2010, and were intrigued by the reactors’ inherent safety. “We both became nuclear engineers because we’re environmentalists,” says Dewan. Besides, her classmate had grown up watching his native West Virginia being devastated by mountaintop removal mining. “So Mark wanted to design a nuclear reactor that’s good enough to shut down the coal industry.”

Then in March 2011, the dangers of the nuclear status quo were underscored yet again. A tsunami knocked out all the cooling systems and backups at Japan’s Fukushima Daiichi plant and sent its 1970s-vintage power reactors into the worst meltdown since Chernobyl. That April, Sorensen launched the first of the molten salt start-up companies, Huntsville-based Flibe Energy. His goal ever since has been to develop and commercialize a Liquid-Fluoride Thorium Reactor — pretty much the same device that was envisioned at Oak Ridge back in the 1960s.

Dewan and Massie founded Transatomic the same month. And other molten salt start-ups soon followed, each building on the basic concept with a host of different design strategies and fuel choices. When Seaborg launched in 2014, for example, Schönfeldt and his colleagues started designing a molten salt Compact Used fuel BurnEr (called CUBE) that would not only run on a combination of spent nuclear fuel and thorium, but also be really, really small by reactor standards. “The fact that you can transport it to the site on the back of a truck is a major upside,” says Schönfeldt, “especially in remote regions.”

TerraPower, meanwhile, decided in 2015 to develop a much larger molten salt device, the Molten Chloride Fast Reactor, as a complement to the company’s ongoing work on its sodium-cooled Traveling Wave Reactor. The new system retains the latter’s ability to burn the widest possible range of fuels — including not just spent nuclear fuel, but also the ordinarily non-fissile uranium-238. (Both designs take advantage of the fact that a uranium-238 nucleus hit by a neutron has a tiny, but non-zero, probability of fissioning.) But unlike in the Traveling Wave Reactor, explains the company’s chief technical officer, John Gilleland, the molten salts’ 700°C-plus operating temperature will allow it to generate the kind of heat needed for industrial processes such as petroleum cracking and plastics making. Industrial process heat currently accounts for about one-third of total energy usage within the US manufacturing sector.

This industrial heat is now produced almost entirely by burning coal, oil or natural gas, says Gilleland. So if you could replace all that with carbon-free nuclear heat, he says, “you could hit the carbon problem in a very striking way.”

Of course, none of this is going to happen tomorrow. The various molten salt companies are still refining their designs by gathering lab data on liquid fuel chemistry, and running massive computer simulations of how the melt behaves when it’s simultaneously flowing and fissioning. The first prototypes won’t be up and running until the mid-2020s at the earliest.

And not all the companies will be there. Transatomic became the molten salt movement’s first casualty in September 2018, when Dewan shut it down. Her company had simply fallen too far behind in its design work relative to competitors, she explains. So even though investors were willing to keep going, she says, “it wouldn’t feel right for us to continue taking their money when I didn’t see a viable path forward for the business side.”

Still, most of the molten salt pioneers say they see reason for cautious optimism. Since at least 2015, the US Department of Energy has been ramping up its support for advanced reactor research in general, and molten salt reactors in particular.

Meanwhile, notes Slaybaugh, licensing agencies such as the US Nuclear Regulatory Commission are gearing up with the computer simulations and evaluation tools they will need when the advanced-reactor companies start seeking approval for constructing their prototypes. “People are looking at these technologies more carefully and more seriously than they have in a long time,” she says.

Perhaps the biggest and most unpredictable barrier is the public’s ingrained fear about almost anything labeled “nuclear.” What happens if people lump in molten salt reactors with older nuclear technologies, and reject them out of hand?

Based on their experience to date, most proponents are cautiously optimistic on this front as well. In Copenhagen, Schönfeldt and his colleagues kept hammering on the why of nuclear power, which was to fight climate change, poverty and pollution. “And we kept telling people the three big advantages of molten salt reactors — no meltdown, no proliferation, burning up nuclear waste,” he says. And slowly, people were willing to listen.

“We’ve moved a long way,” says Schönfeldt. “When we started in 2014, commercial nuclear power was illegal in Denmark. In 2017, we got public funding.”

 

This article originally appeared in Knowable Magazine, an independent journalistic endeavor from Annual Reviews. Sign up for the newsletter.

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  • peterathome

    Is the molten salt the fuel or is it the coolant? If it is the fuel then draining it into a holding tank in case of failure would not make it cool down. Is the reason not to use helium as a coolant that since it is not dense it does not transfer heat well? Thanks

    • Jag_Levak

      “Is the molten salt the fuel or is it the coolant?”

      The molten salts are generally blends of chlorides or fluorides of various metals–lithium, sodium, beryllium, uranium, etc. The salt mixtures can be pure coolant for carrying heat to one point to another, or they can be fuel salts, which would be a base salt carrying fissile metal salts.

      “If it is the fuel then draining it into a holding tank in case of failure would not make it cool down.”

      The molten salt reactors are designed so that the fuel only goes critical (sustaining a chain reaction) while it is in the reactor core. To attain criticality, the fuel has to have sufficient mass, in the right configuration, in a sufficient neutron flux. In the case of thermal-spectrum reactors using moderated (slowed) neutrons, the sufficient neutron flux only exists in the presence of the moderator (eg. graphite) which slows the neutrons down–making them easier for the atoms to catch. Without a moderator, the neutrons are harder for the atoms to catch, so the minimum amount of mass required to sustain a reaction increases greatly. So dumping the fuel would remove it from the moderator in the reactor core, the fuel would no longer be able to reach critical mass, and so there would be no configuration that could sustain a chain reaction. There would still be some decay heat, but 1) most of that comes from fission products, and that can be reduced by removing some of them from the fuel salt on a continuous basis and 2) unlike the design of the reactor–which is optimized for retaining heat (for good reactor efficiency)–the dump tank can be designed for shedding heat. In the case of fast-spectrum molten salt reactors, which don’t have a moderator, the chain reaction in the core is a function of critical mass, a compact configuration, and typically, being surrounded by neutron reflectors, which bounce neutrons back into the core–which effectively makes it operate as if the core is larger than it is and that there is more fuel mass than there is. Draining to a dump tank removes the reflectors and the dump tank is configured to spread the fuel out so that it is no longer in a compact enough configuration to sustain a reaction. And spreading it out also facilitates shedding heat.

      But some molten salt designs don’t even have a dump tank. As liquid fuel salt heats up, it expands, and expansion moves the fissile atoms apart, and it also reduces the amount of fuel in the reactor core, so the amount of reactivity (and thus heat production) decreases as the fuel gets hotter. At some point, it will effectively reach a hot shut-down state, where the amount of reactivity is only producing enough heat to balance heat leakage. This is the maximum temperature the salt can attain, and that point can be set far below temperatures where the salt could boil or where reactor damage occurs.

      “Is the reason not to use helium as a coolant that since it is not dense it does not transfer heat well?”

      Helium is a great heat transfer medium–if it is sufficiently pressurized (if it loses pressure, it also loses cooling capacity). But the main drawback to helium-cooled reactors isn’t the helium coolant, it’s the solid fuel they use.

    • Nom de Plume

      From the article, it’s both. Fusion takes place within the salt medium, and caps at the operating temperature. Cooling takes place as the fuel decays. I get the impression that the cooling plug failsafe is to drain the reactor where it’s not filled with a solid mass once the salt cools.

  • OWilson

    Given today’s rapid technological progress, It’s almost impossible to predict the energy sources 20 years out! Likewise the weather. :)

    I’m especially encouraged that one of my pet predictions may come true, namely, the “ability to consume spent nuclear fuel from traditional nuclear reactors”.

    if we can only overcome the political opposition, from the crowd of “concerned”, luddite usual suspects, who oppose nuclear developement! :)

  • Nom de Plume

    A surprisingly well-written article that looks at pros and cons.

  • http://www.mazepath.com/uncleal/EquivPrinFail.pdf Uncle Al

    1) How do you obtain U-233? That will require rather a lot of electricity.
    2) Tonnes of BeF2!!!! Are you out of your firetrucking minds?
    3) Li-7 in a dense neutron field still gives you tritium.

    • Jag_Levak

      “1) How do you obtain U-233? That will require rather a lot of electricity.”

      It requires neutrons. When thorium 232 absorbs a neutron without fissioning, it becomes thorium 233, which soon decays to protactinium 233, which soon decays to uranium 233.

      “2) Tonnes of BeF2!!!!!!. Are you out of your firetrucking minds?”

      Some molten salt designs would not use beryllium. For the ones that do, what do you think makes that an unsound idea?

      “3) Li-7 in a dense neutron field still gives you tritium.”

      Some molten salt designs would not use lithium. For the ones that do, what problem associated with tritium do you think is unsolvable?

      • http://www.mazepath.com/uncleal/EquivPrinFail.pdf Uncle Al

        I do not see how the summation of coulda, woulda, shoulda is potentially better than real world works in gigawatt/reactor installations. Update 1950s’ conventional reactor designs.

        api(.)intechopen(.)com/media/chapter/43467/media/image15.png
        … Burn thorium added to conventional reactor fuel.

        Current fuel recycling is military – clean actinides and actinide-contaminated beta-decay that must be stored forever for it to decay out (plus a fissionable isotope maximum). A civilian fuel cycle would isolate a clean relatively short half-life beta-decay stream for storage and a gamma-contaminated actinide fuel stream back into the reactor. Try stealing that.

        • Jag_Levak

          “I do not see how the summation of coulda, woulda, shoulda is potentially better than real world works in gigawatt/reactor installations.”

          Technological advancement does not depend on everybody being able to see the advantages of alternative ways of doing things before they are developed. Sometimes, it is a very few beyond those doing the development work who can see the advantages, but that is sufficient. And in this case, the potential advantages of alternative reactors were apparent to Alvin Weinberg–the guy who was the lead inventor of the kind of reactor the Navy wound up using, and which became the basis for our power reactors. The advantages are apparent to the Elysium team, who largely came out of the Navy reactor program. They are apparent to the dozens of teams working on alternative forms of nuclear power, and the investors sinking hundreds of millions of dollars into their work.

          “Update 1950s’ conventional reactor designs.”

          Technology development doesn’t have to be restricted to a single path. Many teams can pursue different approaches, and then the markets will decide the winners. NuScale is adopting basically the approach you suggest, and they have good prospects for getting over the certification hurdle first. But it remains to be seen whether that head start will be enough for them to hang on once they face competition from true advanced reactors.

          “… Burn thorium added to conventional reactor fuel.”

          Adding thorium would do nothing to address the major problems with conventional solid reactor fuel.

          “A civilian fuel cycle would isolate a clean relatively short half-life beta-decay stream for storage and a gamma-contaminated actinide fuel stream back into the reactor.”

          That is basically the approach several of the molten salt teams are going for. They would remove just a few of the more troublesome fission products (particularly neutron poisons) and the fissile and fertile isotopes would simply remain in the reactor to be consumed. But with liquid fuel, chemical processing is easier, there’s no periodic fuel reshuffling required, and all the purification and refueling operations can take place while the reactor is on-line. Other advantages over solid fuel would include low fuel fabrication cost, greater fuel composition flexibility, the ability to ramp power up and down rapidly as part of normal operations, and the big-one; no possibility of meltdown. That last point alone can make a tremendous difference when it comes to public acceptance–and public acceptance is very likely to be a key determinant of marketability.

          • http://www.mazepath.com/uncleal/EquivPrinFail.pdf Uncle Al

            Molten pure Li2BeF4 eats structural alloys – ferritic steels and Hastellloys. It will not be kind to zirconium. DOI:10.1002/9781119323624.ch9

          • Jag_Levak

            “Molten pure Li2BeF4 eats structural alloys – ferritic steels and Hastellloys. It will not be kind to zirconium.”

            There is no molten salt reactor in which that salt would be pure, and there are things that can be added to modify its corrosion potential.
            On page 19 and table 4, pg. 21 of ORNL-TM-6002, you can see that one of their samples dropped the rate of surface degradation to something undetectable after 500 hours of exposure. They also found additives to the alloys which improved their performance. And some molten salt designers (eg. Moltex and Elysium) would be using entirely different kinds of salt. There are also options for including sacrificial elements, making some parts thicker, or simply designing some parts to be replaced on a regular basis. This is all ordinary corrosion management–something we have a great deal of experience with. And even if it all fails in some instance, so what? Some of the fluid leaks out and freezes? That’s still nothing compared to the worst-case accident potentials with old-tech nuclear.

  • Tenje Akhiro
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